Yom Kippur is primarily for women

HH according to the Arizal and Ramchal Yom Kippur is completely dedicated to the feminine Sfira of Malchus, and therefore should really only pertain to women, however since men are also completely dependent on the Malchus, they too are included in the theme of Yom Kippur.

If ever there were to be a proper time, it seems to me that Yom Kippur night would be a proper time for women to put on a talis without a blessing.

Na Nach Nachma Nachman Me'Uman